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Abbreviations: Ileol: isoleucinol Iva: isovaline Vxx: Val/Iva Lxx: Leu/Ile Lxxol: Leuol/Ileol Vxxol: Valol/Ivaol. Ac: acetyl Aib: a-aminoisobutyric acid Oc: octanoyl

Explain: Glu-OMe: The presence of Glu-OMe was supported by the direct connectivity of the OMe-proton signal with the side-chain carboxyl carbon of Glu.